You only have 3 seconds to convince somone to open your email. You have worked hard to craft the perfect subject that will win the open. But if your email message doesn't even reach the inbox it is unlikely that it will ever be opened. Check to be sure you are following the rules for inbox delivery.
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The best way to always ensure delivery to the inbox is to have your subscribers add your from email address to their contacts or address book. The best time to do this is when they first subscribe and are highly motivated to receive your emails. Get step by step whitelist instructions for each ISP.